Tin(II)-functionalization of the archetypal {P8W48} polyoxotungstate.

نویسندگان

  • N V Izarova
  • L Klaß
  • P de Oliveira
  • I-M Mbomekalle
  • V Peters
  • F Haarmann
  • P Kögerler
چکیده

The synthesis of [K(4.5) ⊂ (ClSn(II))8P8W48O184](17.5-), featuring Sn(II) ions in trigonal-pyramidal SnO2Cl environment coordinating to the two inner rims of the wheel-shaped {P8W48}-type polyoxotungstate(vi) archetype, showcases how high chloride ligand concentrations as well as the control of the polyanion solubility via electrolytes and evaporation rates are essential to prevent numerous competing reactions that can hamper the Sn(ii) functionalization of polyoxometalates.

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عنوان ژورنال:
  • Dalton transactions

دوره 44 44  شماره 

صفحات  -

تاریخ انتشار 2015